Determining the structures, acidity and adsorption properties of Al substituted HZSM-5

Determining the locations and distributions of Al substitution in zeolite-based catalysts and catalysis is always very challenging. Despite advanced experimental characterization techniques and improved theoretical models, this issue is not reasonably solved and this is because the locations and distributions of Al substitution in zeolites are more kinetically than thermodynamically controlled. In this work, we computed one Al substitution in the orthorhombic form of MFI (HZSM-5) which contains 12 distinct tetrahedral (T) centers on the basis of a periodic slab model containing 96 T centers including van der Waals dispersion correction (GGA-PBE-D3). For all 12 T centers, there are 48 acidic sites and each site can be considered for the adsorption of probe molecules. Thermodynamically, the energy span of the twelve most stable acidic sites is less than 15 kJ mol-1, and such a small energy difference enables all adjustable possibilities for the locations and distributions of Al substitution under suitable conditions. Excellent agreement between experiment and theory in the adsorption enthalpies of pyridine, methylamine, dimethylamine and trimethylamine shows that the location of Al substitution is most likely at T1, T3, T5, T7 and T11, while much less likely at the often used T12 site. These results provide the basis for identifying Al substitution in new synthesized HZSM-5 catalysts and for studying the acidic site-dependent catalytic activity of HZSM-5 in cracking and hydrogenation reactions.