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Novel LiV(PO4)0.9F1.3 with ultrahigh rate capability and prolonged cycle life
Meichen Zhang1, Yongmao Zhou, Xiaobo Ding
1School of Metallurgy and Environment, Central South University, Changsha 410083, P. R. China. wangjiexikeen@csu.edu.cn.
Abstract:
Novel triclinic LiV(PO4)0.9F1.3, characterized through its crystal lattice expansion, ultrafine primary particle size and uniform carbon coating, was designed and fabricated through regulating the PO4/F ratio. It exhibited excellent electrochemical performance, maintaining 105 mA h g-1 at 50C and 92.9% capacity retention after 500 cycles at 10C due to its superior structural stability, greater charge transfer properties, enhanced electronic conductivity and fast Li+ diffusion kinetics.
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