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Related Concept Videos

Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Structures of Solids02:22

Structures of Solids

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Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
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Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

19.9K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Molecular Comparison of Gases, Liquids, and Solids02:26

Molecular Comparison of Gases, Liquids, and Solids

54.0K
Particles in a solid are tightly packed together (fixed shape) and often arranged in a regular pattern; in a liquid, they are close together with no regular arrangement (no fixed shape); in a gas, they are far apart with no regular arrangement (no fixed shape). Particles in a solid vibrate about fixed positions (cannot flow) and do not generally move in relation to one another; in a liquid, they move past each other (can flow) but remain in essentially constant contact; in a gas, they move...
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Sulfide-Based Solid-State Electrolytes: Synthesis, Stability, and Potential for All-Solid-State Batteries.

Qing Zhang1,2, Daxian Cao2, Yi Ma2

  • 1Kostas Research Institute, LLC at Northeastern University, 141 South Bedford St, Burlington, MA, 01803, USA.

Advanced Materials (Deerfield Beach, Fla.)
|August 24, 2019
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Summary
This summary is machine-generated.

Sulfide solid electrolytes offer high ionic conductivity for all-solid-state batteries. Research addresses challenges in stability, interface, and manufacturing for safer, high-performance energy storage.

Keywords:
characterizationinterfacesmetal sulfidessolid-state batteriesstabilitysynthesis

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Sulfide composites are promising solid electrolytes for all-solid-state batteries due to high ionic conductivity and mechanical properties.
  • Their atomic characteristics, including lower electronegativity and binding energy to Li ions, contribute to excellent ionic conductivity.
  • Significant progress has been made in developing high-performance sulfide solid-state electrolytes.

Purpose of the Study:

  • To provide a comprehensive update on sulfide solid-state electrolytes.
  • To review their properties, synthesis, and application in all-solid-state batteries.
  • To highlight advancements in electrochemical and chemical stability, interface stabilization, and manufacturing.

Main Methods:

  • Review of structural and chemical properties of sulfide solid-state electrolytes.
  • Analysis of synthesis methods for sulfide solid-state electrolytes.
  • Evaluation of electrochemical performance and stability in all-solid-state battery applications.

Main Results:

  • Sulfide solid-state electrolytes exhibit high ionic conductivity, making them attractive for batteries.
  • Challenges remain in achieving wider voltage windows, improved interface/air stability, and cost-effective large-scale production.
  • Ongoing research focuses on overcoming these limitations for practical applications.

Conclusions:

  • Sulfide solid-state electrolytes are key to advancing all-solid-state battery technology.
  • Addressing stability and manufacturing challenges is crucial for their widespread adoption.
  • Continued development promises safer and higher-performance energy storage solutions.