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In Situ Monitoring of the Accelerated Performance Degradation of Solar Cells and Modules: A Case Study for CuIn,GaSe2 Solar Cells
Published on: October 3, 2018
Degradation Analysis of Encapsulated and Nonencapsulated TiO2/PTB7:PC70BM/V2O5 Solar Cells under Ambient Conditions
Edith Osorio1, José G Sánchez1, Leandro N Acquaroli2
1Departament d'Enginyeria Electrònica, Elèctrica i Automàtica, Universitat Rovira i Virgili, Avda. Paisos Catalans 26, 43007 Tarragona, Spain.
Abstract:
Inverted organic cells are promising devices for sustainable and low-cost future electric generation. In this work, we present the degradation mechanisms studied in ITO/TiO2/PTB7:PC70BM/V2O5/Ag inverted organic solar cells (iOSCs) by impedance spectroscopy (IS). Measurements were performed on encapsulated (controlled environment) and nonencapsulated (ambient condition) cells following their temporal evolution under AM1.5 illumination for several voltage biases. From the impedance spectra, analyzed in terms of resistive/capacitive equivalent circuits, we were able to identify that the most sensitive layers inside of the device are contact layers. According with presented, IS technique is useful for determining the materials that have more influence on the degradation of organic solar cells. We demonstrate that IS is a powerful technique to identify the limiting mechanisms and to establish the limiting materials inside of the iOSCs.
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