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One-Pot Synthesis of Hybrid Conjugated Oligomer-Ag Nanoparticles
Timuçin Balkan1, Seda Kizir1, Dönüs Tuncel1
1Department of Chemistry and UNAM-National Nanotechnology Research Center, Institute of Materials Science and Nanotechnology, Bilkent University, 06800 Ankara, Turkey.
Abstract:
Here we report one-pot, straightforward synthesis of hybrid conjugated oligomer-silver nanoparticles (AgNPs) by utilizing tertiary alkyl amine and fluorene-benzothiodiazole-containing conjugated oligomer that both acts as a reducing agent in the reduction of silver ions into metallic silver and as a matrix to accommodate the newly formed AgNPs. By tuning the reaction conditions, it is possible to control the sizes and the structural features of hybrid nanoparticles as either raspberry or core-shell type hybrid structures.
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