Characterization of the Evolution of Crystallization Fouling in Membranes

Liquid-to-air membrane energy exchangers (LAMEEs) are promising in heating, ventilating, and air-conditioning applications because they are able to use semipermeable membranes to transfer heat and moisture between air and liquid desiccant streams. However, the development of crystallization fouling in membranes may pose a great risk to the long-term performance of LAMEEs. The main aim of this paper is to characterize the evolution of crystallization fouling in membranes through the use of both noninvasive and invasive methods. Noninvasive methods are used to study the development of fouling in the LAMEE by monitoring the changes in moisture flux through the membrane and overall moisture-transfer resistance of the LAMEE. On the other hand, invasive methods are implemented to characterize fouled membranes by using optical microscopy and scanning electron microscopy (SEM) to depict the morphology of crystal deposits and energy-dispersive X-ray spectroscopy (EDX) to identify the composition of the deposits. Experiments are performed by using air to dehydrate MgCl₂(aq) at two operating conditions of low and high fouling rates. The results show that the moisture flux decreases and the moisture-transfer resistance increases more considerably during the test at the high fouling rate than in the test at the low fouling rate. SEM micrographs show that cake crystal deposits cover the membrane surface in the test at the high fouling rate, whereas only few crystal particles are observed on the membrane in the test at the low fouling rate. Furthermore, the crystal deposits undergo more structural changes in the tests at the high fouling rate than in the tests at the low fouling rate, possibly because of the higher moisture transfer rate through the membrane in the tests at the high fouling rate. Finally, the SEM-EDX analysis confirms that the crystal deposits primarily consist of Mg, Cl, and O elements.