Pd NP-Decorated N-Rich Porous Organic Polymer as an Efficient Catalyst for Upgradation of Biofuels

Hydrodeoxygenation process is a potential route for upgrading biofuel intermediates, like vanillin, which is obtained in huge quantities through the chemical treatment of the abundant lignocellulosic biomass resources of nature, and this is attracting increasing attentions over the years. Herein, we report the grafting of palladium nanoparticles at the surface of porous organic polymer Pd-PDVTTT-1 synthesized through the co-condensation of 1,3,5-triallyl-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione and divinylbenzene in the presence of radical initiator under solvothermal reaction conditions. The Pd-PDVTTT-1 material has been characterized thoroughly by powder X-ray diffraction, nitrogen sorption, ultra-high-resolution transmission electron Microscopy, Fourier-transform infrared spectroscopy, ¹³C MAS NMR, and X-ray photoelectron spectroscopy analyses. High surface area together with good thermal stability of the Pd-PDVTTT-1 material has motivated us to explore its potential as heterogeneous catalyst in the hydrodeoxygenation of vanillin for the production of upgraded biofuel 2-methoxy-4-methylphenol in almost quantitative yield and high selectivity (94%).