Related Experiment Video
Updated: Jan 20, 2026
08:37
Le Chatelier's Principle: Effect of Concentration and Temperature on Chemical Equilibrium
Published on: April 30, 2023
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Reply: Clockwise and Counterclockwise Le Fort I Movements Influence Nasolabial Morphology Differently
Plastic and Reconstructive Surgery
|August 29, 2019
Abstract
No abstract available in PubMed .
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Le Châtelier's Principle
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Source: Laboratory of Dr. Lynne O'Connell — Boston College
When the conditions of a system at equilibrium are altered, the system responds in such a way as to maintain the equilibrium. In 1888, Henri-Lewis Le Châtelier described this phenomenon in a principle that states, "When a change in temperature, pressure, or concentration disturbs a system in chemical equilibrium, the change will be counteracted by an alteration in the equilibrium composition."
This experiment demonstrates Le...
When the conditions of a system at equilibrium are altered, the system responds in such a way as to maintain the equilibrium. In 1888, Henri-Lewis Le Châtelier described this phenomenon in a principle that states, "When a change in temperature, pressure, or concentration disturbs a system in chemical equilibrium, the change will be counteracted by an alteration in the equilibrium composition."
This experiment demonstrates Le...
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A system at equilibrium is in a state of dynamic balance, with forward and reverse reactions taking place at equal rates. If an equilibrium system is subjected to a change in conditions that affects these reaction rates differently (a stress), then the rates are no longer equal and the system is not at equilibrium. The system will subsequently experience a net reaction in the direction of a greater rate (a shift) that will re-establish the equilibrium. This phenomenon is summarized by Le...
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Le Chatelier's Principle: Changing Temperature
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Consistent with the law of mass action, an equilibrium stressed by a change in concentration will shift to re-establish equilibrium without any change in the value of the equilibrium constant, K. When an equilibrium shifts in response to a temperature change, however, it is re-established with a different relative composition that exhibits a different value for the equilibrium constant.
To understand this phenomenon, consider the elementary reaction:
To understand this phenomenon, consider the elementary reaction:
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For gas-phase equilibria, changes in the concentrations of reactants and products can occur with altered volume and pressure. The partial pressure, P, of an ideal gas is proportional to its molar concentration, M.
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