Related Experiment Video
Updated: Jan 20, 2026

Microfluidic Synthesis of Microgel Building Blocks for Microporous Annealed Particle Scaffold
Published on: June 16, 2022
Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of
Viktoria K Muravieva1,2, Yakov M Gayfulin1, Carmelo Prestipino2
1Nikolaev Institute of Inorganic Chemistry SB RAS, 3, Acad. Lavrentiev ave., 630090, Novosibirsk, Russia.
Abstract:
Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6-x Mox Se8 (CN)6 ]n- (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond-length distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS, and DFT calculations.
Related Concept Videos
09:34Microfluidic Synthesis of Microgel Building Blocks for Microporous Annealed Particle Scaffold
12:30Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
07:43Cell-Free Protein Synthesis System for Building Synthetic Cells
10:37Spatial Separation of Molecular Conformers and Clusters
09:45Modification and Functionalization of the Guanidine Group by Tailor-made Precursors
Building Blocks of Accounting

