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Assessing the impacts of dynamic soft-templates innate to switchable ionic liquids on nanoparticulate green rust
Jian Zheng1, Xiao-Ying Yu, Manh-Thuong Nguyen
1Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA 99354, USA.
Abstract:
This experimental and theoretical study investigates how dynamic solvation environments in switchable ionic liquids regulate the composition of nanoparticulate green rust. A custom microfluidic device enables in situ X-ray absorption spectroscopy to elucidate characterization of the solvent structure and speciation of reaction intermediates of air-sensitive nanoparticles growing in solution.
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