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Updated: Jan 20, 2026
Crystal Field Theory - Octahedral Complexes
On mean-field theories of dynamics in supercooled liquids
Marco Baity-Jesi1, David R Reichman1
1Department of Chemistry, Columbia University, New York, New York 10027, USA.
Abstract:
We develop a hybrid numerical approach to extract the exact memory function K(t) of a tagged particle in three-dimensional glass-forming liquids. We compare the behavior of the exact memory function to two mean-field approaches, namely, the standard mode-coupling theory and a recently proposed ansatz for the memory function that forms the basis of a new derivation of the exact form of K(t) for a fluid with short-ranged interactions in infinite dimensions. Each of the mean-field functions qualitatively and quantitatively share traits with the exact K(t), although several important quantitative differences are manifest.
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