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Updated: Jan 20, 2026
Alkali Metals: Physical Properties, Ionization Energies and Reactivity
Ba8SrPb24O24Cl18: the first alkali-earth metal lead(ii) oxyhalide with an intriguing multimember-ring layer
Zhuang Li1, Shengzi Zhang, Wenhao Xing
1Beijing Center for Crystal Research and Development, Key Lab of Functional Crystals and Laser Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. jyao@mail.ipc.ac.cn.
Abstract:
The first alkali-earth metal lead(ii) oxyhalide Ba8SrPb24O24Cl18 characterized by fascinating multimember-ring layers has been discovered. Theoretical and experimental investigations illustrate that Ba8SrPb24O24Cl18 exhibits a moderate band gap of 3.09 eV, incongruent melting behavior and birefringence of 0.014@1064 nm. This discovery may offer new ideas for regulating the optical properties of oxyhalides and broadening their structural diversity.
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