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Updated: Jan 20, 2026

Author Spotlight: Characterizing Porous Materials for Aiding the Development of Robust Metal-Organic Frameworks with Adsorption Behavior
Published on: March 8, 2024
Tailoring the pore geometry and chemistry in microporous metal-organic frameworks for high methane storage working
Kai Shao1, Jiyan Pei1, Jia-Xin Wang1
1State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China. bin.li@zju.edu.cn gdqian@zju.edu.cn.
Abstract:
We realized that tailoring the pore size/geometry and chemistry, by virtue of alkynyl or naphthalene replacing phenyl within a series of isomorphic MOFs, can optimize methane storage working capacities, affording an exceptionally high working capacity of 203 cm3 (STP) cm-3 at 298 K and 5-80 bar.
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