Spatial homogeneity and heterogeneity of ambient air pollutants in Tehran

To investigate spatial inequality of ambient air pollutants and comparison of their heterogeneity and homogeneity across Tehran, the following quantitative indicators were utilized: coefficient of divergence (COD), the 90^th percentile of the absolute differences between ambient air pollutant concentrations and coefficient of variation (CV). Real-time hourly concentrations of particulate matter (PM) and gaseous air pollutants (GAPs) of twenty-two air quality monitoring stations (AQMSs) were obtained from Tehran Air Quality Control Company (TAQCC) in 2017. Annual mean concentrations of PM_2.5, PM_10-2.5, and PM₁₀ (PM_X) ranged from 21.7 to 40.5, 37.3 to 75.0 and 58.0 to 110.4 μg m^-3, respectively. Annual mean PM_2.5 and PM₁₀ concentrations were higher than the World Health Organization air quality guideline (WHO AQG) and national standard levels. NO₂, O₃, SO₂ and CO annual mean concentrations ranged from 27.0 to 76.8, 15.5 to 25.1, 4.6 to 12.2 ppb, and 1.9 to 3.8 ppm over AQMSs, respectively. Our generated spatial maps exhibited that ambient PM_X concentrations increased from the north into south and south-western areas as the hotspots of ambient PM_X in Tehran. O₃ hotspots were observed in the north and south-west, while NO₂ hotspots were in the west and south. COD values of PM_X demonstrated more results lower than the 0.2 cut off compared to GAPs; indicating high to moderate spatial homogeneity for PM_X and moderate to high spatial heterogeneity for GAPs. Regarding CV approach, the spatial variabilities of air pollutants followed in the order of O₃ (87.3%) > SO₂ (65.2%) > CO (61.8%) > PM_10-2.5 (52.5%) > PM_2.5 (48.9%) > NO₂ (48.1%) > PM₁₀ (42.9%), which were mainly in agreement with COD results, except for NO₂. COD values observed a statistically (P < 0.05) positive correlation with the values of the 90^th percentile across AQMSs. Our study, for the first time, highlights spatial inequality of ambient PM_X and GAPs in Tehran in detail to better facilitate establishing new intra-urban control policies.