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Structural features associated with multiferroic behavior in the RX3(BO3)4 system
H Zhang1, S Liu1, C S Nelson2
1Department of Physics, New Jersey Institute of Technology, Newark, NJ 071022, United States of America.
None:
The magnetoelectric effect in the RX3(BO3)4 system (R = Ho, Eu, Sm, Nd, Gd; X = Fe, Al) varies significantly with the cation R despite very similar structural arrangements. Our structural studies reveal a symmetry reducing tilting of the BO3 planes and of the FeO6 polyhedra in the systems exhibiting low magnetic field induced electric polarization. Neutron scattering measurements reveal a lack of magnetic ordering indicating the primary importance of the atomic structure in the multiferroic behavior of this system.
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