Hospital wastewaters treatment: Fenton reaction vs. BDDE vs. ferrate(VI)

Tomáš Mackuľak1, Roman Grabic2, Viera Špalková1

  • 1Institute of Chemical and Environmental Engineering, Faculty of Chemical and Food Technology, Slovak University of Technology, Radlinského 9, 812 37, Bratislava, Slovakia.

Insights

Hospital wastewater contains micropollutants and antibiotic-resistant bacteria. Advanced oxidation processes, like the modified Fenton reaction and boron-doped diamond electrode, effectively removed over 90% of these contaminants.

Area of Science:

  • Environmental Chemistry
  • Water Treatment Technologies
  • Microbiology

Background:

  • Hospital wastewater is a significant source of micropollutants, including pharmaceuticals and antibiotic-resistant bacteria.
  • These contaminants pose risks to aquatic ecosystems and human health.
  • Effective treatment methods are crucial for hospital wastewater management.

Purpose of the Study:

  • To investigate the presence and concentrations of 74 pharmaceuticals and antibiotic-resistant bacteria in Slovakian and Czech hospital wastewaters.
  • To evaluate the efficacy of advanced oxidation processes (AOPs) for treating these highly polluted wastewaters.
  • To compare different AOPs, including modified Fenton reaction, ferrate(VI), and boron-doped diamond electrode oxidation.

Main Methods:

  • Micropollutant analysis using in-line solid-phase extraction coupled with liquid chromatography-tandem mass spectrometry (SPE-LC-MS/MS).
  • Antibiotic-resistant bacteria detection via cultivation on selective media.
  • Application and performance assessment of modified Fenton reaction, ferrate(VI), and boron-doped diamond electrode oxidation.

Main Results:

  • High concentrations of pharmaceuticals like cotinine, bisoprolol, metoprolol, tramadol, sulfamethoxazole, and ranitidine were detected.
  • Modified Fenton reaction and boron-doped diamond electrode oxidation achieved >90% removal of most micropollutants.
  • All tested AOPs successfully eliminated antibiotic-resistant bacteria from the wastewater.

Conclusions:

  • Hospital wastewater contains a complex mixture of pharmaceuticals and antibiotic-resistant bacteria.
  • Advanced oxidation processes, particularly modified Fenton reaction and boron-doped diamond electrode, show high potential for effective hospital wastewater treatment.
  • These methods offer a promising solution for mitigating the environmental impact of hospital effluents.

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