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Mineralization of aniline in aqueous solution by sono-activated peroxydisulfate enhanced with PbO semiconductor
Wen-Shing Chen1, Yu-Cheng Shih1
1Department of Chemical and Materials Engineering, National Yunlin University of Science & Technology, 123 University Road, Section 3, Douliou, Yunlin, 640, Taiwan.
Abstract:
Oxidative degradation of aniline in aqueous solution was performed by the sono-activated peroxydisulfate coupled with PbO process, wherein a dramatic synergistic effect was found. Experiments were carried out in the batch-wise mode to investigate the influence of various operation parameters on the sonocatalytic behavior, such as ultrasonic power intensity, peroxydisulfate anion concentrations and PbO dosages. According to the scavenging effect of ethanol, methanol and tert-butyl alcohol, the principal oxidizing agents were presumed to be sulfate radicals descended from peroxydisulfate anions, activated via ultrasound or sonocatalysis of PbO. Based on the results attained from gas chromatograph-mass spectrometer, it was hypothesized that aniline was initially oxidized into iminobenzene radicals, followed with formation of nitrosobenzene, p-benzoquinonimine and nitrobenzene respectively. Condensation of nitrosobenzene with aniline generated azobenzene. Phenol was detected as one of degradation intermediates, which was sequentially converted into hydroquinone and p-benzoquinone.
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