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Updated: Jan 19, 2026
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Phase Transitions and Effect of Intermolecular Forces
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Entropy production as a tool for characterizing nonequilibrium phase transitions
C E Fernández Noa1, Pedro E Harunari1, M J de Oliveira1
1Instituto de Física da Universidade de São Paulo, 05314-970 São Paulo, Brazil.
Physical Review. E
|September 11, 2019
Summary
Entropy production characterizes nonequilibrium phase transitions, revealing system irreversibility. Continuous and discontinuous transitions exhibit unique entropy production hallmarks, aiding classification.
Area of Science:
- Statistical Mechanics
- Nonlinear Dynamics
- Complex Systems
Background:
- Equilibrium phase transitions are well-characterized by order parameters.
- Nonequilibrium systems possess irreversible dynamics that influence transition properties.
- Entropy production is a key metric, being zero in equilibrium and positive out of equilibrium.
Purpose of the Study:
- To characterize nonequilibrium phase transitions using entropy production.
- To bridge the gap in understanding irreversible dynamics' role in phase transitions.
- To establish a general framework for classifying these transitions.
Main Methods:
- Analysis of both discontinuous and continuous phase transitions.
- Inclusion of regular and complex topologies.
- Application of mean-field theory (MFT) and beyond MFT.
- Focus on Z_{2} symmetry systems.
Main Results:
- Entropy production provides a distinct hallmark for different types of phase transitions.
- A general description of entropy production portraits for Z_{2} symmetry systems under MFT was developed.
- The majority vote model was used to exemplify predictions.
Conclusions:
- Entropy production offers a systematic way to describe and classify nonequilibrium phase transitions.
- This approach highlights the system's irreversibility.
- The findings provide a new perspective on understanding complex system dynamics.
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