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Updated: Jan 19, 2026

Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange
Published on: June 23, 2023
Synthesis of o-carborane-functionalized metal-organic frameworks through ligand exchanges for aggregation-induced
Sangdon Choi1, Ha-Eun Lee1, Chan Hee Ryu2
1Department of Chemistry and BK21Plus Research Team, Chungbuk National University, Cheongju, 28644, Korea. minkim@chungbuk.ac.kr.
Abstract:
The carborane (CB)-functionalized ligand was installed in a variety of MOFs through postsynthetic ligand exchange processes. This methodology is a general method for preparing o-CB-functionalized MOFs with known frameworks. Furthermore, the photoluminescence (PL) spectra revealed intriguing aggregation-induced emission (AIE) features following the systematic incorporation of o-CB functionalities into framework-type materials.
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