Temporal trends in polychlorinated naphthalene emissions from sintering plants in China between 2005 and 2015

The Chinese Government has established stringent policies since 2005 to control SO₂, particulate matter, and NO_x emissions from sintering plants with the aim of tackling severe air pollution in China. Notably, sintering is also important sources of polychlorinated naphthalenes (PCNs), but it is not clear whether the air pollution control policies have led to decreased PCN emissions. In this study, the PCN concentrations in 144 stack gas, 87 discarded fly ash, and 24 desulfurization by-product samples from 24 Chinese sintering plants were determined. This study revealed that desulfurization processes decreased PCN emissions by 47.2%-72.2%. However, these PCNs were not completely eliminated, and transformed to desulfurization by-product. PCN emission in such previously ignored solid residues, including of desulfurization by-product and fine particles, produced in the process of cutting down air pollutants emissions from Chinese sintering plants between 2005 and 2015 was found contained 324 kg, and these residues therefore need to be managed better than currently. Furthermore, PCN concentrations were higher from produced in old plants than produced in new plants, so it is necessary to increase the rate at which out-of-date sintering plants are eliminated. Phasing out old sintering processes decreased total PCN emissions in China by 1549 kg between 2005 and 2015.