High-dispersion zero-valent iron particles stabilized by artificial humic acid for lead ion removal

Nano zero-valent iron (nZVI), as a high-efficiency adsorbent for heavy metals, often suffers being oxidized and assembling together due to small size and super reactivity, further decreasing its adsorption performance and limiting application ranges. Herein, we have designed a novel adsorbent with high-dispersion nZVI stabilized by as-prepared artificial humic acid (AHA-nZVI) derived from hydrothermal humification (HTH) technology. Introduction of artificial humic acid (A-HA) can effectively reduce the oxidation and agglomeration of nZVI, leading to superior kinetic removal efficiency of Pb²⁺ (> 99.2%) and huge Langmuir removal capacity of 649.0 mg/g. The combination of nZVI and A-HA (contained abundant functional groups, i.e. -OH and -COOH) via C-O-Fe bonding makes nZVI have good dispersion and oxidation resistance. Multiple interaction mechanisms including reduction reaction, complexation and co-precipitation between heavy metals and AHA-nZVI samples are realized. Overall, AHA-nZVI is a promising material for high-performance heavy metal contaminated water treatment.