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Published on: December 25, 2015
Pilot study of nitrogen removal from landfill leachate by stable nitritation-denitrification based on zeolite
Zhenguo Chen1, Xiaojun Wang1, Xiaokun Chen1
1School of Environment and Energy, South China University of Technology, Guangzhou 510006, China; The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, China.
Abstract:
A pilot (about 1 m3/d) process consisting of pre-denitrification and zeolite biological aerated filter (ZBAF) was established and run for nitrogen removal of landfill leachate. The results showed that stable nitritation and denitrification was achieved for landfill leachate with removal efficiency of Chemical Oxygen Demand (CODCr), ammonium and total nitrogen (TN) of 53.2 ± 3.0%, 93.5 ± 2.4% and 74.7 ± 9.4%, respectively. Based on the ammonium adsorption equilibrium by zeolite, stable free ammonia could be maintained for inhibition of nitrite oxidizing bacteria (NOB) and dominance of ammonia oxidizing bacteria (AOB) in ZBAF, resulting in efficient nitritation with a nitrite accumulation ratio higher than 90.0% and an average nitrite production rate of 1.387 kg NO2--N m-3 day-1. High-throughput sequencing analysis further revealed enrichment of AOB and elimination of NOB in ZBAF. Compared to two-stage anoxic-oxic process, the pilot-scale process could save approximate 5000 mg/L glucose (about 3.10 US dollar/m3) with almost similar TN removal performance. All results obtained demonstrated the feasibility of the pilot process, which might be highly promising for the nitritation and denitrification of low C/N landfill leachate in the future.
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