Kinetic study and performance comparison of TiO₂-mediated visible-light-responsive photocatalysts for the...

Fungi are highly survived with exceptional resistance to environmental stress. Conventional fungicides are quite efficient, but the increase in use raises severe environmental problems. In this study, environmentally friendly TiO₂-mediated visible-light-responsive photocatalysts, namely N-TiO₂, N-T-TiO_2, C-TiO₂, and Pd-C-TiO₂, were used to compare the performance of disinfecting a mold fungi Aspergillus niger. Key parameters, including photocatalyst dosage, the initial fungal concentration, and visible-light intensity, affecting the disinfecting process, was investigated. A new developed Light-responsive Modified Hom's (LMH) kinetic model incorporating visible-light intensity and photocatalyst light-absorption coefficient was firstly used to predict such photocatalytic process in fungal inactivation. Among the photocatalysts, Pd-C-TiO₂ showed the highest inactivation performance against fungi, followed by C-TiO₂, N-T-TiO_2, and N-TiO₂. In general, inactivation increased with increasing photocatalyst dosage and light intensity while decreased with increasing initial fungal concentration. For kinetic modeling, the LMH model supports the hypothesis that photocatalyst performance toward visible-light-driven fungal inactivation primarily depends on the light-absorption capacity of the photocatalyst. In conclusion, mold fungi Aspergillus niger are effectively disinfected by TiO₂-mediated visible-light-responsive photocatalysts, and such fungal inactivation process could be predicted by LMH kinetic model.