Targeted Construction of Amorphous MoS_x with an Inherent Chain Molecular Structure for Improved Pseudocapacitive...

Owing to low ion/electron conductivity and large volume change, transitional metal dichalcogenides (TMDs) suffer from inferior cycle stability and rate capability when used as the anode of lithium-ion batteries (LIBs). To overcome these disadvantages, amorphous molybdenum sulfide (MoS_x ) nanospheres were prepared and coated with an ultrathin carbon layer through a simple one-pot reaction. Combining X-ray photoelectron spectroscopy (XPS) with theoretical calculations, MoS_x was confirmed as having a special chain molecular structure with two forms of S bonding (S^2- and S₂ ^2- ), the optimal adsorption sites of Li⁺ were located at S₂ ^2- . As a result, the MoS_x electrode exhibits superior cycle and rate capacities compared with crystalline 2H-MoS₂ (e.g., delivering a high capacity of 612.4 mAh g^-1 after 500 cycles at 1 A g^-1 ). This is mainly attributed to more exposed active S₂ ^2- sites for Li storage, more Li⁺ transfer pathways for improved ion conductivity, and suppressed electrode structure pulverization of MoS_x derived from the inherent chain-like molecular structure. Quantitative charge storage analysis further demonstrates the improved pseudocapacitive contribution of amorphous MoS_x induced by fast reaction kinetics. Moreover, the morphology contrast after cycling demonstrates the dispersion of active materials is more uniform for MoS_x than 2H-MoS₂ , suggesting the MoS_x can well accommodate the volume stress of the electrode during discharging. Through regulating the molecular structure, this work provides an effective targeted strategy to overcome the intrinsic issues of TMDs for high-performance LIBs.