Impact of Operating Conditions on Measured and Predicted Concentration Polarization in Membrane Distillation

Concentration polarization (CP) occurs in almost all membrane-based separation processes. In this study, the concentration profile of the dissolved salt has been accurately characterized using a previously developed laser-based spectrophotometric method which had a spatial resolution of 4.5 μm. The objective of the current work was to probe the concentration profile of the solute and analyze the impact of operating parameters, such as feed concentration, hydrodynamic conditions, and feed temperature, on the solute concentration profile in the boundary layer. This study also examined the validity of the conventional approach, where semi-empirical models are used to estimate the boundary layer thickness (BLT) and concentration polarization coefficient (CPC)-based on experimental results. Nusselt correlations were developed specifically for the membrane cell and validated through experimental observations at the operating conditions used in this study. A key finding of this study is that the conventional approach of estimating the effect of CP severely underpredicts the BLT and CPC. The results of this study highlight the need to develop new methods to estimate the BLT and CPC as the conventional approach of using semi-empirical Nusselt and Sherwood correlations does not agree with experimental observations obtained for a membrane distillation system employed in this study.