A comparative study of biological activated carbon based treatments on two different types of municipal reverse...

A study was conducted to understand the impact of reverse osmosis concentrate (ROC) characteristics on the efficacy of biological activated carbon (BAC) based treatments for removing organics and nutrients from two ROC streams (ROC_a derived from municipal waste input with high salinity, and ROC_b derived from domestic waste plus industrial trade waste with markedly lower salinity). Fluorescence excitation and emission matrix spectra and molecular weight analysis demonstrated that ROC_a and ROC_b had a significantly different composition of organic compounds due to the petrochemical processing and abattoir waste compounds in ROC_b. Although the sequence of coagulation, UV/H₂O₂ and BAC gave the highest organic removal from the two ROCs (67% DOC for ROCa and 62% for ROCb), UV/H₂O₂ followed by BAC achieved satisfactory removal (>55%) for both ROC types. Sequential treatment involving coagulation gave better phosphorus removal (>90%) than any single treatment (<65%). Total nitrogen (TN) removal was fairly low (<50%) for all the treatment options and the salinity level had insignificant impact on nitrogen removal. Analysis of bacterial communities suggested that higher phosphorus removal and lower total nitrogen and nitrate removal from ROC_b than ROC_a was related to the presence of various denitrifying or phosphorus accumulating bacteria in the BAC.