Rice Husk-Derived Activated Carbons for Adsorption of Phenolic Compounds in Water

Activated carbons are synthesized from rice husk by one- and two-step pyrolysis. In general, two-step pyrolysis produces a higher yield of activated carbons. The yield of activated carbon decreases with the increase of mass ratio of KOH and biomass, which has a significant impact on the development of surface area and porosity. The maximum S _BET (2138 m² g^-1) is achieved with micro- and mesoporous structures, which is favored for the adsorption process. The activated carbons can efficiently remove phenol from water by a few minutes. In particular, the maximum adsorption capacity (201 mg g^-1) is achieved due to the excellent surface textural properties. The Langmuir model can better define the adsorption isotherm. The high correlation coefficient value (R ² = 0.9991) indicates a monolayer adsorption behavior. The adsorption process can be well-fitted by the pseudo-second-order model. Herein, the phenol molecules pass into the internal surface via liquid-film-controlled diffusion, so the behavior of phenol adsorption onto activated carbons is mainly controlled via chemisorption. In addition, the functional groups on the outer surfaces of activated carbons can attract the phenol molecules onto their internal surface via the "π-π dispersion interaction" and "donor-acceptor effect."