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Imaging material functionality through three-dimensional nanoscale tracking of energy flow.

Milan Delor1,2,3, Hannah L Weaver2,4, QinQin Yu4

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Physical Chemistry

Background:

  • Energy carrier transport is fundamental to material and biochemical functions.
  • Observing energy flow requires ultrasmall and ultrafast spatio-temporal resolution.
  • Material morphology and disorder significantly influence energy carrier pathways.

Purpose of the Study:

  • To develop a non-invasive optical scheme for tracking energy carriers in four dimensions (spacetime).
  • To correlate energy carrier distributions with material morphology at nanometre precision.
  • To elucidate the impact of disorder on energy flow in semiconductors.

Main Methods:

  • Utilized non-resonant interferometric scattering to detect minute changes in material polarizability.
  • Developed a four-dimensional spatio-temporal mapping technique for energy carriers.
  • Applied the method to polyacene, silicon, and perovskite semiconductors.

Main Results:

  • Visualized exciton, charge, and heat transport in various semiconductor materials.
  • Demonstrated that morphological boundaries in perovskites exhibit depth-dependent resistivity, impeding lateral transport.
  • Quantified the influence of structural disorder on energy flow dynamics.

Conclusions:

  • The developed optical scheme enables precise, non-invasive tracking of energy carriers.
  • Material morphology critically dictates energy transport pathways and efficiency.
  • Strategies for interpreting energy transport in disordered systems can guide the design of defect-tolerant materials for advanced semiconductor applications.