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Updated: Jan 6, 2026

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Synthesis and Properties of a Bay-Annulated-Indigo Tetramer Based on Low-Cost Spiro[Fluorene-9,9'-Xanthene] Core
Bao-Yi Ren1, Yan-Mei Tan2, Chang-Liang Sun3
1College of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang 110142, China. renbaoyi@syuct.edu.cn.
Abstract:
A three-dimensional bay-annulated-indigo (BAI) tetramer has been prepared by appending BAI units onto a low-cost spiro[fluorene-9,9'-xanthene] (SFX) core. The target compound 4BAI-SFX exhibits strong and broad absorption in the visible region covering the range of 450~700 nm. The electrochemical measurement illuminates the characteristics of a deep lowest unoccupied molecular orbital (LUMO) level and multiple redox states of 4BAI-SFX. These results suggest that 4BAI-SFX should be a selectable electron-transporting material for eco-friendly organic semiconductors.
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