Preparation and flocculation properties of modified alginate amphiphilic polymeric nano-flocculants

The novel nano-flocculants were synthesized through a conjugation of dodecylamine with partly oxidized sodium alginate. The structures of the flocculants were characterized by FTIR, ¹HNMR, TGA, and EA. The flocculants possessed amphiphilic structures and formed nano-micelles through self-assembly in water. The nano-micelles showed rod-like shapes about 100 nm. Removal rates of the flocculants for Pb²⁺ and bisphenol A were determined under different conditions, showing the removal rates as high as 97.20% and 88.66% for Pb²⁺ and bisphenol A, respectively. The flocculation mechanisms were revealed by X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM), respectively. Isotherm adsorption studies indicated that the flocculation for Pb²⁺ accorded with the Langmuir single-layer adsorption model, and for bisphenol A accorded with the Freundlich multi-layer adsorption model. The quasi-second-order kinetic model was suitable for describing the adsorption kinetics. The new nano-flocculant was a promising agent for removing both heavy metal ions and organic pollutants of wastewater.