Related Experiment Video
Updated: Jan 5, 2026

Integrating a Triplet-triplet Annihilation Up-conversion System to Enhance Dye-sensitized Solar Cell Response to Sub-bandgap Light
Published on: September 12, 2014
Fine Modulation of the Higher-Order Excitonic States toward More Efficient Conversion from Upper-Level Triplet to
Yuwei Xu1, Cong Wang1, Xuehong Zhou1
1Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices , South China University of Technology , Guangzhou 510640 , P.R. China.
Abstract:
Hot exciton luminogens capable of harvesting nonemissive triplet excitons via reverse intersystem crossing from high-order triplet (hRISC) to singlet have great potential in high-efficiency fluorescent organic light-emitting diodes (OLEDs). Although spin-orbit coupling (SOC) is regarded as a key factor affecting the RISC process, its effects on hot exciton materials are poorly understood. Herein, we design and synthesize two blue-emitting hot exciton luminogens, PABP and PAIDO, to study this issue by modulating the excited-state properties. Theoretical and experimental research contributions demonstrate that a stronger SOC between energetically close S1 (π-π*) and T (T3, n-π*) of PAIDO gives rise to faster and more efficient hRISC in comparison to that of PABP, leading to a higher external quantum efficiency and a higher exciton utilization efficiency. Crucially, the experimentally measured hRISC rate (khRISC) of hot exciton materials is on the order of 107 s-1, which is much faster than that of the thermally activated delayed fluorescence materials.
Related Concept Videos
Deactivation Processes: Jablonski Diagram
UV–Vis Spectroscopy: Molecular Electronic Transitions
Interpreting ¹H NMR Signal Splitting: The (n + 1) Rule
¹H NMR: Interpreting Distorted and Overlapping Signals
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are...
Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
Photochemical Electrocyclic Reactions: Stereochemistry
Selection Rules: Photochemical Activation

