Thermal Reshaping of Gold Microplates: Three Possible Routes and Their Transformation Mechanisms

The thermal stability of Au micro/nanomaterials (AuMNLs) has always been a hot topic because their physicochemical properties, like surface plasmon resonance and catalytic activity, are closely related to their morphology or exposed crystal planes which are heat-sensitive. In this study, we made careful and systematic investigation of thermal deformation and reshaping of individual Au microplates (AuMPs) using atomic force microscopy. We found that AuMPs could transform into walled AuMPs (WAuMPs) and concave AuMPs (CAuMPs) at just 300 °C, which are thermodynamically and kinetically favorable products, respectively. A small fraction of AuMPs, named invariable AuMPs (IAuMPs), remained intact. However, both CAuMPs and IAuMPs can be converted to WAuMPs if the temperature is further increased. We also showed that melting of AuMPs begins from vertices and the boundaries between the top and side plane, rather than only side crystal planes as envisaged before. Finally, we performed a series of electrochemical studies showing that WAuMPs exhibited substantially higher electrocatalytic conversion of methanol at lower formal potential compared to intact AuMPs. This work shows that thermal reshaping of Au is far more complicated as was expected before. It also demonstrates how thermal reshaping can be used to improve electrocatalytic performance of Au and potentially other MNLs.