Interaction Forces between Water Droplets and Solid Surfaces across Air Films

Wetting of solid surfaces occurs when the intervening air film between a water droplet and a solid surface ruptures. Although this rupturing phenomenon is well known, the underlying mechanism has not yet been well understood. In this work, the rupture of intervening air films is systematically studied by measuring the spatiotemporal thickness profiles of the air films between droplets of deionized water and flat solid surfaces using a synchronized triwavelength reflection interferometry microscope. It has been shown that the critical rupture thickness of the air film (h _c) depends on the surface hydrophobicity of solid surfaces. The h _c value was increased from 50 nm on a hydrophobic surface having an equilibrium water contact angle (θ_w) of 96° to 1.42 μm on a hydrophilic surface having a θ_w of 25°. In addition, an increase in the critical rupture thickness with decreasing surface hydrophobicity was found to be applicable not only to chemically treated quartz surfaces but also to a variety of natural mineral surfaces. By determining the pressure within the air films, we have shown that a strong attractive force is present between water droplets and hydrophilic surfaces, thereby accelerating the draining of air films. The measured forces might be of electrostatic origin, and the forces become less attractive with increasing hydrophobicity of solid surfaces. The present result provides a fundamental insight into the rupture of air films from the perspective of surface forces.