An Organic Crystal with High Elasticity at an Ultra-Low Temperature (77 K) and Shapeability at High Temperatures

Organic single crystals with elastic bending capability and potential applications in flexible devices and sensors have been elucidated. Exploring the temperature compatibility of elasticity is essential for defining application boundaries of elastic materials. However, related studies have rarely been reported for elastic organic crystals. Now, an organic crystal displays elasticity even in liquid nitrogen (77 K). The elasticity can be maintained below ca. 150 °C. At higher temperatures, the heat setting property enables us to make various shapes of crystalline fibers based on this single kind of crystal. Through detailed crystallographic analyses and contrast experiments, the mechanisms behind the unusual low-temperature elasticity and high-temperature heat setting are disclosed.