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Terbium Triangle Bridged by a Triazole Nitronyl Nitroxide Radical with Single-Molecule-Magnet Behavior
Jian Yun Shi1, Ming Ze Wu1, Peng Yun Chen1
1Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Materials Chemistry, Ministry of Education, College of Chemistry , Tianjin Normal University , Tianjin 300387 , P. R. China.
Abstract:
An unprecedented cyclic TbIII-radical cluster, [Tb3(hfac)6(4-Me-3-NITtrz)2(OH)3] (1), has been self-assembled from Tb(hfac)3·2H2O and 4-Me-3-NITtrz in the presence of Cu(hfac)2·2H2O. Alternating-current magnetic studies show that the Tb3 cluster displays a dual slow relaxation of magnetization behavior under a zero direct-current (dc) field and a single relaxation process under an induced dc field with an effective energy barrier of 14 K, representing the first triangle 2p-4f cluster with a slow magnetic relaxation property.
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