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Acidity of 1-Alkynes02:42

Acidity of 1-Alkynes

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The acidic strength of hydrocarbons follows the order: Alkynes > Alkenes > Alkanes. The strength of an acid is commonly expressed in units of pKa — the lower the pKa, the stronger the acid. Among the hydrocarbons, terminal alkynes have lower pKa values and are, therefore, more acidic. For example, the pKa values for ethane, ethene, and acetylene are 51, 44, and 25, respectively, as shown here.
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Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

48.4K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Alkyl Halides02:45

Alkyl Halides

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Structural Properties
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
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Ionic Bonds00:42

Ionic Bonds

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Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
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Ions as Acids and Bases02:54

Ions as Acids and Bases

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Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
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Complexation Equilibria: Factors Influencing Stability of Complexes01:09

Complexation Equilibria: Factors Influencing Stability of Complexes

756
In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
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Updated: Jan 5, 2026

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
12:27

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes

Published on: September 8, 2013

11.2K

YHO, an Air-Stable Ionic Hydride.

Nicolas Zapp1, Henry Auer1, Holger Kohlmann1

  • 1Inorganic Chemistry , Leipzig University , Leipzig 04109 , Germany.

Inorganic Chemistry
|October 19, 2019
PubMed
Summary
This summary is machine-generated.

Yttrium hydride oxide (YHO) has been successfully synthesized in bulk form, revealing a stable, semiconducting material with potential applications. This novel compound exhibits remarkable air stability and slow hydrolysis, making it promising for functional material development.

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Area of Science:

  • Solid-state chemistry
  • Materials science
  • Inorganic chemistry

Background:

  • Metal hydride oxides are an emerging class of materials.
  • Lanthanide hydride oxides (LnHO) are known, but yttrium hydride oxide (YHO) has primarily been observed in thin films.
  • Bulk synthesis of YHO is crucial for exploring its properties and applications.

Purpose of the Study:

  • To synthesize bulk yttrium hydride oxide (YHO).
  • To characterize the structure and properties of YHO.
  • To evaluate the stability and potential applications of YHO.

Main Methods:

  • Synthesis via reactions of Y2O3 with hydrides, YH3 with CaO, or metathesis of YOF with alkali metal hydrides.
  • Structural analysis using X-ray and neutron powder diffraction.
  • Property evaluation through quantum-mechanical calculations (DFT) and in situ X-ray diffraction.

Main Results:

  • YHO was successfully synthesized in bulk form with an anti-LiMgN type structure (distorted fluorite).
  • YHO exhibits semiconducting properties with a band gap of 2.8 eV and significant ionic bonding.
  • The material demonstrates remarkable stability in air, with decomposition starting above 500 K, and slow hydrolysis in water.

Conclusions:

  • Bulk YHO can be synthesized using various methods.
  • YHO possesses a unique crystal structure, semiconducting behavior, and considerable ionic character.
  • The exceptional air stability and slow hydrolysis of YHO make it a promising candidate for functional material applications.