Effective adsorption of diclofenac sodium from neutral aqueous solution by low-cost lignite activated cokes
Liyuan Wu1, Chunxiao Du2, Juan He1
1Beijing Engineering Research Center of Sustainable Urban Sewage System Construction and Risk Control, Beijing University of Civil Engineering and Architecture, Beijing 100044, China; Beijing Advanced Innovation Center For Future Urban Design, Beijing 100044, China.
Abstract:
Activated cokes have attracted great interest inwater treatment to remove organic pollutants due to their low cost and specific textural properties. In this study, adsorptive removal of diclofenac sodium (DCF) from neutral aqueous solution by available lignite activated cokes (LACs) was reported for the first time. Diclofenac sodium could be quickly removed from aqueous solution by LAC-2, with the maximum Langmuir adsorption capacity qm of 224 mg/g at pH 6.5. Characterization results (including scanning electron microscopy, transmission electron microscopy, elemental analyses, Boehm titrations, N2 adsorption-desorption isotherms and Fourier transform infrared spectroscopy) and a series of adsorption kinetics, adsorption isotherms model studies revealed that high porosity with developed macro- and micropore structures on LAC-2, as well as high content of phenolic groups, could obviously enhance the DCF adsorption capacity and rate. Moreover, LAC-2 showed high affinity towards DCF at low concentrations, as well as good reusability after three adsorption-desorption cycles. pH effect studies revealed that hydrogen-bonding interaction plays an important role during adsorption, accompanied with certain contribution from electrostatic interaction and π-π interaction. This study indicates the promising potential of LAC-2 as an efficient, low-cost and recyclable material for DCF removal from water bodies.
