Enhanced Photothermal Conversion by Hot-Electron Effect in Ultrablack Carbon Aerogel for Solar Steam Generation

Ecofriendly, highly effective, and low-cost solar steam generation has great potential in the applications of power generation, seawater desalination, and industry wastewater treatment. Solar steam generation requires an evaporator that has strong light absorption over a wide-frequency band (200-3000 nm), high photothermal conversion efficiency, and good thermal insulation to avoid excessive heat loss. Herein, foam-strengthened ultrablack carbon aerogels (CAs) with micropores, mesopores, and macropores were prepared using freeze drying. The small-size conductor effect in ultrablack CAs could increase the surface electron concentration, leading to the increase of light absorption and ultimately enhancing photothermal conversion efficiency. Consequently, under 1 sun illumination, dried CA-5 exhibited a fast temperature rise rate and the highest thermal equilibrium temperature of 87.6 °C among CAs, the equilibrium temperature is 20.8 °C higher than that of the foam. Besides, CA-5 exhibited a high water evaporation rate of 1.29 kg m^-2 h^-1 under only 1 sun illumination. To further increase the hot-electron effect, CO₂ activation was implemented. The highest water evaporation rate among activated CAs (ACAs) was 1.37 kg m^-2 h^-1, which is about 2.85 times higher than that of pure water. The highest water evaporation efficiency was 87.51%, which is better than most of the previously reported evaporation efficiencies. Besides the hot-electron enhancement effect, ACAs with thermal insulation, mechanical strength, and thermal stability show great potential for producing fresh water from seawater, industrial wastewater, and even concentrated acidic or alkaline solutions.