Controllable Synthesis of Porous Cu-BTC@polymer Composite Beads for Iodine Capture

The efficient and safe capture of radioactive iodine (¹²⁹I or ¹³¹I) is of great significance in nuclear waste disposal. Here, we report millimeter-scale poly(ether sulfone) composite beads loaded with porous Cu-BTC [Cu₃(BTC)₂, BTC = 1,3,5-benzenetricarboxylate] (Cu-BTC@PES), prepared by a phase inversion method for the removal of volatile iodine. Three kinds of Cu-BTC@PES composite beads were obtained with different Cu-BTC contents of 48.6, 60.2, and 71.9%, respectively. While maintaining crystallinity, the composite beads exhibited higher I₂ vapor adsorption capacity (639 mg/g) in the form of iodine molecules. The iodine absorption up to 260 mg/g and the adsorption was followed Langmuir isotherm and pseudo-second-order kinetic model. Furthermore, the composite beads can still absorb more than 85% of iodine after 3 cycles of regeneration with excellent recyclability. The resulting Cu-BTC@PES composite beads show great potential for the sustainable removal of radioactive iodine.