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Updated: Jan 5, 2026

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Family of closed-form solutions for two-dimensional correlated diffusion processes
Haozhe Shan1, Rubén Moreno-Bote2, Jan Drugowitsch3
1Program in Neuroscience, Harvard University, Boston, Massachusetts 02115, USA and Center for Brain Science, Harvard University, Cambridge, Massachusetts 02138, USA.
Abstract:
Diffusion processes with boundaries are models of transport phenomena with wide applicability across many fields. These processes are described by their probability density functions (PDFs), which often obey Fokker-Planck equations (FPEs). While obtaining analytical solutions is often possible in the absence of boundaries, obtaining closed-form solutions to the FPE is more challenging once absorbing boundaries are present. As a result, analyses of these processes have largely relied on approximations or direct simulations. In this paper, we studied two-dimensional, time-homogeneous, spatially correlated diffusion with linear, axis-aligned, absorbing boundaries. Our main result is the explicit construction of a full family of closed-form solutions for their PDFs using the method of images. We found that such solutions can be built if and only if the correlation coefficient ρ between the two diffusing processes takes one of a numerable set of values. Using a geometric argument, we derived the complete set of ρ's where such solutions can be found. Solvable ρ's are given by ρ=-cos(π/k), where k∈Z^{+}∪{+∞}. Solutions were validated in simulations. Qualitative behaviors of the process appear to vary smoothly over ρ, allowing extrapolation from our solutions to cases with unsolvable ρ's.
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