Porous, flexible, and core-shell structured carbon nanofibers hybridized by tin oxide nanoparticles for efficient...

Carbon based nanofibrous materials are considered to be promising sorbents for the CO₂ capture and storage. However, the precise control of porous structure with flexibility still remains a challenging task. In this research, we report a simple strategy to develop tin oxide (SnO₂) embedded, flexible and highly porous core-shell structured carbon nanofibers (CNFs) derived from polyacrylonitrile (PAN)/polyvinylidene fluoride (PVDF) core-shell nanofibers.

PAN/PVDF core-shell solutions were electrospun using co-axial electrospinning process. The as spun PAN core, and PVDF shell, with an appropriate amount of SnO₂, fibers were stabilized followed by carbonization to develop SnO₂ embedded highly porous and flexible core-shell structured CNFs.

The optimized CNFs membrane shows a prominent CO₂ capture capacity of 2.6 mmol g^-1 at room temperature, excellent CO₂ selectivity than N₂, and a remarkable cyclic stability. After 20 adsorption-desorption cycles, the CO₂ capture capacity retains >95% of the preliminary value showing the long-term stability and practical worth of the final product. The loading of SnO₂ nanoparticles in the carbon matrix not only enhanced the thermal stability of the precursor nanofibers, their surface characteristics, and porous structure to capture CO₂ molecules, but also improves the flexibility of the CNFs by serving as a plasticizer for single-fiber-crack connection. Meaningfully, the flexible SnO₂ embedded core-shell CNFs with excellent structural stability can prevail the limitations of annihilation and collapse of structures for conventional adsorbents, which makes them strongly useful and applicable. This research introduces a new route to produce highly porous and flexible materials as solid adsorbents for CO₂ capture.