Aqueous Lubrication with the Molecularly Confined Films of Silicone-Based Amphiphilic Block Copolymer Aggregates

The confined film structures and tribological properties of the dilute aqueous solution of a silicone-based amphiphilic block copolymer, bis-isobutyl poly(ethylene glycol) (PEG)-14/amodimethicone (BIPA) copolymer, between mica surfaces were investigated. The BIPA copolymer existed as positively charged water-soluble aggregates in the solution. The adsorption behavior of the BIPA copolymer aggregates on a mica surface from solution was studied using an atomic force microscope (AFM); the result showed the immediate formation of a uniform adsorbed BIPA copolymer layer, followed by the gradual deposition of BIPA aggregates on the top of the adsorbed layer. Friction measurements were carried out using the surface forces apparatus (SFA) for the confined films of BIPA copolymer solution between mica surfaces, which revealed two different sliding film structures depending on the elapsed time after surface preparation. The sliding film consisting of two adsorbed BIPA copolymer layers was obtained for a relatively short elapsed time (not longer than 3 h), which had an extremely low friction coefficient μ (of the order of 10^-5). The sliding film on the following day (elapsed time of approximately 24 h) had the structure of a deposited/kinetically trapped BIPA aggregate layer confined between the opposing adsorbed layers, and the μ values were within the range from 10^-4 to 10^-3. Our results suggest that the different elapsed time ranges and resulting absence or presence of the intervening layer of trapped aggregates between the absorbed layers determine the tribological properties of the confined films. Molecular friction mechanisms are discussed for the two sliding structures, which give insight into using amphiphilic block copolymer aggregates for a new class of aqueous lubrication system to design extremely low friction interfaces.