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Updated: Jan 5, 2026
Preparation of Monodomain Liquid Crystal Elastomers and Liquid Crystal Elastomer Nanocomposites
Published on: February 6, 2016
Solvent-Free Fabrication of an Elastomeric Epoxy Resin Using Glycol Lignin from Japanese Cedar
Kenta Ono1, Osamu Tanaike1, Ryo Ishii1
1Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology (AIST), 4-2-1 Nigatake, Miyagino-ku, Sendai, Miyagi 983-8551, Japan.
Abstract:
In this study, a simple formulation of softwood-derived glycol lignin (GL)-based epoxy resin with a high GL content of greater than 50 wt % was demonstrated by direct mixing with poly(ethylene glycol) diglycidyl ether (PEGDGE), an aliphatic epoxide, without using any solvent. Because the GL powder produced from poly(ethylene glycol) (PEG400) solvolysis of Japanese cedar softwood meal was a PEG400-modified lignin (GL400), a strong affinity between PEG counterparts facilitates the uniform mixing of GL400 with PEGDGE, and one component uncured GL400/PEGDGE epoxy resin was prepared at a relatively lower temperature (100 °C) than the curing temperature (130 °C). The epoxy curing reaction was monitored by 1H NMR and Fourier transform infrared spectroscopies. The physical and mechanical properties of the epoxy resins with different GL400 contents were then evaluated. The developed resins exhibited good flexibility and elasticity depending on the GL400 content.
