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Updated: Jan 5, 2026
Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
Published on: October 18, 2019
Facile assembly of bifunctional, magnetically retrievable mesoporous silica for enantioselective cascade reactions
Zhongrui Zhao1, Fengwei Chang1, Tao Wang1
1Key Laboratory of Resource Chemistry of Ministry of Education, Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China. ghliu@shnu.edu.cn.
Abstract:
An integrated immobilization to encapsulate the Pd/C-coated magnetic nanoparticles within the chiral Ru/diamine-functionalized silica shell for the construction of a bifunctional magnetic catalyst is developed. This catalyst realizes a synergistic Suzuki cross-coupling/asymmetric transfer hydrogenation and a successive reduction/asymmetric transfer hydrogenation for the preparation of chiral aromatic alcohols.
