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Modelling PAHs removal in activated sludge process: effect of disintegration.

I Mozo1, M Bounouba2, E Mengelle2

  • 1LISBP, Université de Toulouse, CNRS, INRA, INSA, Toulouse, France E-mail: yolaine.bessiere@insa-toulouse.fr; TOTAL SA - CSTJF, Avenue Larribau, 64000 Pau, France.

Water Science and Technology : a Journal of the International Association on Water Pollution Research
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Sludge disintegration significantly enhances polycyclic aromatic hydrocarbons (PAHs) removal by increasing dissolved and colloidal matter (DCM), which improves PAH availability for degradation in wastewater treatment.

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Area of Science:

  • Environmental Science
  • Environmental Engineering
  • Biotechnology

Background:

  • Polycyclic Aromatic Hydrocarbons (PAHs) are persistent organic pollutants found in wastewater.
  • Activated sludge processes are commonly used for wastewater treatment but can be limited in PAH removal.
  • Sludge disintegration methods are being explored to enhance pollutant removal.

Purpose of the Study:

  • To evaluate the impact of sludge disintegration on PAH removal in activated sludge systems.
  • To investigate the role of dissolved and colloidal matter (DCM) in PAH removal after disintegration.
  • To develop a model for predicting PAH availability and degradation influenced by sludge disintegration.

Main Methods:

  • Utilized two laboratory-scale bioreactors, one with and one without a sonication disintegration system.
  • Performed mass balances to quantify PAH removal efficiencies.
  • Developed and applied a model to assess DCM content and its effect on PAH degradation.

Main Results:

  • Sludge disintegration significantly improved overall PAH removal, particularly for higher molecular weight PAHs.
  • Disintegration led to an increase in dissolved and colloidal matter (DCM) content.
  • The developed model effectively predicted improved PAH degradation trends and identified DCM as the primary driver.

Conclusions:

  • Sludge disintegration is an effective strategy for enhancing PAH removal in activated sludge.
  • Increased DCM following disintegration is the key factor improving PAH availability and apparent degradation.
  • The developed model provides valuable insights into the mechanisms of PAH removal enhancement.