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Calcium-based efficient cathode-ray scintillating metal-organic frameworks constructed from π-conjugated luminescent
Jian Lu1, Hui-Fang Wu, Wen-Fei Wang
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zfk@fjirsm.ac.cn gcguo@fjirsm.ac.cn.
Abstract:
Efficient cathode-ray scintillating metal-organic frameworks are constructed from a π-conjugated luminescent motif and light Ca(ii) ions. The luminescence self-quenching pathway has been effectively hindered through coordination. In situ vacuum ultraviolet fluorescent spectra have shown the excitons recombining in the scintillation process for the first time.
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