Phoretic Liquid Metal Micro/Nanomotors as Intelligent Filler for Targeted Microwelding

Micro/nanomotors (MNMs) have emerged as active micro/nanoplatforms that can move and perform functions at small scales. Much of their success, however, hinges on the use of functional properties of new materials. Liquid metals (LMs), due to their good electrical conductivity, biocompatibility, and flexibility, have attracted considerable attentions in the fields of flexible electronics, biomedicine, and soft robotics. The design and construction of LM-based motors is therefore a research topic with tremendous prospects, however current approaches are mostly limited to macroscales. Here, the fabrication of an LM-MNM (made of Galinstan, a gallium-indium-tin alloy) is reported and its potential application as an on-demand, self-targeting welding filler is demonstrated. These LM-MNMs (as small as a few hundred nanometers) are half-coated with a thin layer of platinum (Pt) and move in H₂ O₂ via self-electrophoresis. In addition, the LM-MNMs roaming in a silver nanowire network can move along the nanowires and accumulate at the contact junctions where they become fluidic and achieve junction microwelding at room temperature by reacting with acid vapor. This work presents an intelligent and soft nanorobot capable of repairing circuits by welding at small scales, thus extending the pool of available self-propelled MNMs and introducing new applications.