Synthesis, Structures, and Solution Dynamics of Titanium and Zirconium Complexes Carrying a Bis(indolyl) and Two...

Indolyl is the anionic species obtained from the deprotonation of the N-H group of indole. Group 4 transition-metal complexes that carry indolyl-based polydentate ligands represent promising homogeneous catalysts for, e.g., olefin polymerization, hydroamination, and nitrogen-fixation reactions due to the weak π-donation and electron-withdrawing properties, as well as the low basicity of indolyl. In this study, we systematically investigated the synthesis and structures of titanium and zirconium complexes that carry deprotonated 2,2'-bis(indolyl)methane ligands (henceforth: bis(indolyl) ligands) and two diethylamido ligands. We found that the coordination geometry of the indolyl nitrogen atom in such bis(indolyl) ligands is affected by the steric impact of the substituents attached to the central aromatic ring. Moreover, we examined the dynamics of such bis(indolyl) ligands in solution for the corresponding zirconium complexes, and the mechanism was discussed in conjunction with DFT calculations. The results of this study suggest that bis(indolyl) ligands may also serve as coordinatively flexible ancillary ligands, and indicate the feasibility of an expansion from bis(indolyl) to bis(indolyl)-donor ligands.