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Jordi Segura1,2, Rosa Ventura2, José Antonio Pascual1
1Integrative Pharmacology and Systems Neuroscience Research Group, IMIM (Hospital del Mar Medical Research Institute), Barcelona, Spain.
An athlete attempted to tamper with a urine sample using alcohol in the 1990s. This case pioneered new doping control methods and forensic analysis, including gas chromatography/combustion/isotopic ratio mass spectrometry (GC/C/IRMS).
Area of Science:
- Sports Science
- Forensic Chemistry
- Anti-Doping
Background:
- A notable doping case from the late 1990s involved the physical manipulation of a urine sample.
- The sample, containing a prohibited substance, was altered by the addition of an alcoholic beverage.
Purpose of the Study:
- To report on a unique doping case from the late 1990s.
- To highlight the novel aspects and scientific advancements introduced by this case in doping control.
Main Methods:
- Analysis of a tampered urine sample containing a prohibited substance and an alcoholic beverage.
- Involvement of an enologist in the B sample confirmation process.
- Forensic inspection of the sample container.
- Application of early gas chromatography/combustion/isotopic ratio mass spectrometry (GC/C/IRMS).
Main Results:
- The case was considered a sanctioned manipulation under the regulations of the time.
- The prohibited substance was deemed an explanatory factor for the sample's condition.
- The case led to the first public hearing by the Court of Arbitration for Sport (CAS).
Conclusions:
- This case represented a significant development in anti-doping efforts.
- It introduced novel analytical techniques and procedural aspects to doping control.
- The public hearing facilitated broader understanding and engagement with doping control processes.
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