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Plasmonic Oligomers with Tunable Conductive Nanojunctions.

Xiaoyan Li1, Jieli Lyu1, Claire Goldmann1

  • 1Laboratoire de Physique des Solides , CNRS, Univ. Paris-Sud, Université Paris-Saclay , 91405 Orsay Cedex, France.

The Journal of Physical Chemistry Letters
|November 5, 2019
PubMed
Summary

Researchers developed a new method to weld gold nanoparticles using other metals, creating tailored plasmonic structures. This technique precisely controls hot spot characteristics for advanced plasmonic applications.

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Area of Science:

  • Nanotechnology
  • Materials Science
  • Plasmonics

Background:

  • Engineering plasmonic hot spots is crucial for plasmonic nanoparticle applications.
  • Welding nanoparticles into complex structures offers targeted plasmonic symmetries.
  • Controlling nanoparticle welding and hot spot properties remains a challenge.

Purpose of the Study:

  • To present an innovative method for connecting gold nanoparticles using a secondary metal.
  • To demonstrate control over plasmonic hot spot characteristics through controlled welding.

Main Methods:

  • Assembling gold bipyramids in a tip-to-tip configuration to form short chains.
  • Growing metallic junctions (silver or palladium) between gold nanoparticles in a second step.
  • Monitoring chain formation and metal deposition using UV/vis spectroscopy.

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  • Characterizing plasmonic properties via electron energy loss spectroscopy.
  • Main Results:

    • Successfully formed gold nanoparticle chains with metallic junctions.
    • Silver bridges induced a significant red shift of longitudinal plasmon modes into the mid-infrared.
    • Palladium addition caused a red shift with substantial plasmon damping.

    Conclusions:

    • The developed method enables precise engineering of plasmonic hot spots.
    • The choice of the bridging metal (silver or palladium) tunes the plasmonic response.
    • This approach offers a pathway to design custom plasmonic structures for specific applications.